Fifth Semester

Fundamentals concepts – scope and limitations of thermodynamics.Thermodynamic systems – different types of systems – macroscopic and microscopic analysis – continuum – Properties – state – processes.thermodynamics equilibrium – Equation of state of an ideal gas – PVT System – Real gas relations – Compressibility factor – Law of corresponding states. 10 II Laws of thermodynamics- Zeroth law of thermodynamics – Thermal equilibrium – Concept of temperature – Temperature scales – Thermometry – Perfect gas temperature scales. – Thermometry – Perfect gas temperature scales. Work and heat – First law of thermodynamics – Concept of energy _ First law for closed and open systems – Specific heats – internal energy and enthalpy – Steady flow energy equations _ Joule Thompson effect.